Perovskite cell
Product
Definition:
Perovskite cells are a new type
of compound thin-film solar cell that uses perovskite-type materials as a
light-absorbing layer. They belong to the third generation of solar cells and
can be categorized as pure perovskite cells or perovskite tandem cells.
Perovskite cells can be stacked with either crystalline silicon cells or
thin-film cells, with a theoretical maximum stacking capacity of four layers. With
technological advancements, full perovskite tandems are also possible,
potentially leading to complete independence from crystalline silicon cells.
Perovskite materials possess numerous excellent properties, such as high
absorption coefficient, high carrier mobility, and high defect tolerance. These
properties contribute to a range of advantages for their cells, including
simple preparation, low cost, and ultra-light and ultra-thin design.
Furthermore, by optimizing their chemical composition, perovskite materials
with varying characteristics can be produced for diverse applications, such as
semi-transparent solar cells and colored photovoltaic glass. The bandgap of
these materials can be tuned by varying the types and proportions of their
constituent substances, enabling them to cover a wide spectral absorption range
extending into the infrared region. They also possess the advantages of long
carrier diffusion distances and high mobility.
Features:
1.Efficiency
Advantage
According to data from the Qianzhan
Industry Research Institute, the theoretical efficiency limit for crystalline
silicon cells is 29.43%, for TOPCon cells is 27.5%, and for HJT cells is
28.2%-28.7%. Currently, the efficiency of TOPCon cells in mass production has
reached 24.6%, and the average efficiency of HJT cells in mass production has
exceeded 24%. The room for improvement in the efficiency of crystalline silicon
cells in mass production is limited, and a bottleneck may be reached within the
next decade. Perovskite cells, on the other hand, offer rapid efficiency
improvements and a high ceiling. Single-junction cells can reach 31%, exceeding
the limit of crystalline silicon cells. Dual-junction stacks can reach 40%, and
triple-junction stacks can reach 50%.
2.
Cost Advantage
The perovskite photovoltaic industry chain
is shorter than that of crystalline silicon and inherently features an
integrated approach. By sourcing chemical raw materials, final module
production can be completed and delivered from a single factory, significantly
shortening the production lead time and reducing overall costs. Of particular
note, the cost of perovskite raw materials typically accounts for only 5-8% of
the cost of perovskite modules, and their price is stable, far lower than the
silicon material in crystalline silicon modules, which accounts for over
one-third of the cost and experiences significant price fluctuations.
Furthermore, according to GCL Optoelectronics, as perovskite modules scale up,
module costs will drop to RMB¥0.7-0.75 /W when
production capacity reaches 1GW, module efficiency reaches 17%, and cell sizes
reach 2.4m².
Challenges
to Commercialization:
1. Large-Area Fabrication
The conversion efficiency of perovskite
cells decreases significantly with increasing area. The main reasons include:
1) non-uniform deposition of thin films
over large areas;
2) perovskite degradation at the edges of
the P2 scribe line;
3) dead zones in the cell subcell
connections; and
4) increased series resistance and
decreased parallel resistance in the module. Large-scale fabrication of
perovskite cells faces numerous challenges, the most significant of which is
perovskite film fabrication.
2. Stability
Currently, the maximum continuous
illumination duration of perovskite cells is approximately 10,000 hours. Based
on an average sunlight duration of 4 hours, the theoretical lifespan is only
6.8 years, significantly lower than the 25-year theoretical lifespan of
crystalline silicon cells. Stability is the biggest bottleneck for perovskite
cells, and no effective solution currently exists. The reasons are:
1) Their structure: perovskites are ionic
structures with weak bonds;
2) Reaction characteristics: the perovskite
formation temperature is low and the energy required for reverse decomposition
is low;
3) The external environment: water, oxygen,
and sunlight can easily damage the crystal structure.